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Refer to the guide <Record Music from Spotify/Streaming Sites to iTunes>.
Go to ITUNES LIBRARY option on the main page and click Recorded icon to find the recorded music from Radio/Rdio. Select the music that you wish to transfer to iDevice.
Using the USB cable, connect iPhone/iPad/iPod to PC/Mac. The connected device will be detected and a prompt will be shown as below, here we make iPhone for example.
a. Right click the checked music and then select “Add to” option and then select the iDevice to which you wish to export the music.
b. Another way to export music is by clicking the Export icon at the top-right corner and then selecting the iDevice from drop-down menu to which the music is to be exported.